ELTE LEEAC

Eötvös Loránd University
Laboratory of Electrochemistry &
Electroanalytical Chemistry

Cyclic voltammetric and nanogravimetric studies of NADP+ redox transformations on a yeast-modified platinum electrode

The paper authored by A. Róka and G. Inzelt is published in Electrochemistry Communications (2014, vol. 45, pp. 9–12).

Abstract:

The dominant voltammetric response of a yeast suspension in neutral or slightly alkaline media can be assigned to the redox transformations of nicotinamide adenine dinucleotide (NAD+/NADH) and nicotinamide adenine dinucleotide phosphate (NADP+/NADPH). By immobilization of yeast on platinum, a stable electrode can be prepared which shows an electrocatalytic activity towards the reduction of NADP+ and the reoxidation of the product formed. Reversible cyclic voltammetric responses were obtained. The peak currents depend practically linearly on the NADP-Na2 concentration and on the square root of the scan rate. The surface mass changes accompanying the redox transformations were monitored by an electrochemical quartz crystal nanobalance.

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doi:10.1016/j.elecom.2014.05.006